I have the 95 3200 SCR, what works for me is: turn on bilge blower for several minutes (blah, blah, blah, we all know this part).
Start the engine that has the power steering first, on mine its the starboard engine. Turn key but not all the way to start, just enough for the electrical gauges to work. Push throttle level one full press all the way up, back all the way down, and then 1/4 up. Since the boat is new to you, at this point check if the choke has closed the carb. If it hasn't it, you need to figure and fix that. If carb/choke check out okay, turn the ignition key all the way, if engine doesn't start after a few seconds, stop, and push the throttle up a bit and back down. These 5.7 motors are like old Chevy engines, have to prime them a bit like HavaMax said. On new or newly rebuilt carbs, they should start with a single pump of the throttle. Repeat for the other motor.
Now the fun, check for idle and timing. The specs should be on the top cover of your engine. Note, the idle check must be performed while the engine is in gear, not in neutral. Engine timing should also be spot on. Have fun and welcome to the party.
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