you have a short.
for that much amp to cook a wire that big, means there was no fuse in front of it.
I bet if you follow the battery cable route to the starter, you will find then cable laying on the Y-pipe or exhaust manifold, and the insulator burned clear through shorting the wire to ground.
The other possibility is a alternator rectifier bridge burned out, this regulates the output of the alternator.
Also a dead battery with shorted plates inside.
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